Preheat oven to 325 F.
Generously grease and flour two 9-inch round cake pans. Set aside.
In a medium bowl, whisk together flour, Baking Soda, Baking Powder, Cocoa Powder, and Salt. Set aside.
In a large bowl, combine the sugar and vegetable oil.
Mix in the Eggs, Buttermilk, Vanilla, and Red Food Coloring until combined.
Stir in the hot Coffee and White Vinegar.
Combine the wet ingredients with the dry ingredients a little at a time, mixing after each addition, just until combined. The batter will be thin.
Pour the batter evenly into each pan.
Bake on the middle rack of 30-40 minutes or until a toothpick inserted in the center comes out clean without moist crumbs clinging to it. Don't leave the cake in the oven too long since the cake will continue to cook as it cools.
Let both pans cool on a cooling rack until the pans are warm to the touch.
Slide a knife or an offset spatula around the inside of the pans to loosen the cake from the pans.
Gently remove the cakes from both pans. Allow them to finish cooling.
Frost the cake with cream cheese frosting when the cakes have cooled completely.